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surface-active agent

Chemical compound that modifies physical, electrical, or chemical characteristics of surface of solid, also surface tensions of solids or liquids. Used in froth flotation and in detergency. Characteristically, its heteropolar molecules are attracted to a specific type of surface in a mixture where one group forms polar monolayer attachments while the rest of the molecule points outward and changes the relations between the surface and the ambient phase. These relations may change lyophilic and aerophilic attraction, surface tension, intermiscellar grouping, emulsification, and froth foaming. Surfaceactive agents include cleaners (e.g., soaps); water repellants (e.g., greases); dispersants and emulsifiers (e.g., glue); and additives adsorbed at interfaces between liquids (usually aqueous) and external gas, liquid or solid phases, with resulting change in interfacial tension. Three electrochemical types are unionized molecule, anion, and cation. Important characteristics of surface-active agents are solubility in the medium 3187 and effects of specific adsorption at interfaces. Such agents either provide anchorage between phases or form a barrier, according to their flocculating or dispersing effect.

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